Design, syntheses, complexation, and electrochemistry of polynuclear metallodendrimers possessing internal metal binding loci

George R. Newkome, Anil K. Patri, Luis A. Godínez

Resultado de la investigación: Contribución a una revistaArtículo

38 Citas (Scopus)

Resumen

Extended, branched monomers possessing bipyridine moieties were synthesized by the use of high dilution conditions, then utilized in the assembly of macromolecular constructs. Dendrimers with four internal bipyridine units at precise locations within the superstructure were transformed into their [Ru(bpy′)(bpy)2]2+ (bpy = 2,2′-bipyridine) complexes. The absorption spectra and cyclic voltammetry measurements of these polynuclear dendritic bipyridine ruthenium(II) complexes were measured and used to confirm their composition.

Idioma originalInglés
Páginas (desde-hasta)1445-1451
Número de páginas7
PublicaciónChemistry - A European Journal
Volumen5
N.º5
EstadoPublicada - 1 dic 1999

Huella dactilar

Dendrimers
Ruthenium
Electrochemistry
Complexation
Dilution
Cyclic voltammetry
Absorption spectra
Monomers
Metals
Chemical analysis

Citar esto

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Design, syntheses, complexation, and electrochemistry of polynuclear metallodendrimers possessing internal metal binding loci. / Newkome, George R.; Patri, Anil K.; Godínez, Luis A.

En: Chemistry - A European Journal, Vol. 5, N.º 5, 01.12.1999, p. 1445-1451.

Resultado de la investigación: Contribución a una revistaArtículo

TY - JOUR

T1 - Design, syntheses, complexation, and electrochemistry of polynuclear metallodendrimers possessing internal metal binding loci

AU - Newkome, George R.

AU - Patri, Anil K.

AU - Godínez, Luis A.

PY - 1999/12/1

Y1 - 1999/12/1

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AB - Extended, branched monomers possessing bipyridine moieties were synthesized by the use of high dilution conditions, then utilized in the assembly of macromolecular constructs. Dendrimers with four internal bipyridine units at precise locations within the superstructure were transformed into their [Ru(bpy′)(bpy)2]2+ (bpy = 2,2′-bipyridine) complexes. The absorption spectra and cyclic voltammetry measurements of these polynuclear dendritic bipyridine ruthenium(II) complexes were measured and used to confirm their composition.

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KW - Cyclic voltammetry

KW - Dendrimers

KW - Metallo-dendrimers

KW - Reuthenium

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